The French fashion house have signed the star up for a campaign to promote two new handbags.
WWD have an image of the 32-year-old, who can be seen leaning on a brown leather bag with black detail.
The star looks stunning ,wearing a dress from the Louis Vuitton Fall/Winter 2013 collection with her platinum crop slightly tousled and much darker make-up than usual, berry-red lips and defined brows that really set off her slick of black eyeliner.
The new bags she is promoting are the W and the Capucines and the campaign is set to break in Marie Claire France, which is due out on August 2.
This will be followed by several September and October issues of magazines worldwide.
Photographer Peter Lindbergh lensed the campaign, styled by Sam McKnight and Stéphane Marais behind the hair and make-up.
Images Courtesy of Louis Vuitton